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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 3
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Original Articles

Economical and Convenient Carbonyl Transposition Approach Toward a 2‐Arylcycloheptanone Derivative

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Pages 299-310 | Received 28 Jul 2005, Published online: 19 Aug 2006
 

Abstract

A convenient, straightforward, and easy access to 2(2,3‐dimethoxy‐phenyl)cycloheptanone, which employs an heteroatom‐facilitated ortho‐lithiation coupled to a carbonyl transposition strategy, is reported. The synthetic approach avoids using very expensive reagents or difficult‐to‐prepare starting materials.

Acknowledgment

The authors gratefully acknowledge financial support provided by CONICET, Fundación Antorchas, and ANPCyT (Project 06‐12532) and also thank SECyT‐UNR. A. B. J. B. especially acknowledges ANPCyT and CONICET for her fellowship.

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