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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 11
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Original Articles

Rapid Microwave‐Promoted Base‐Free Suzuki Coupling Reaction of Sodium Tetraphenylborate with Hypervalent Iodonium Compounds in Water

Jie Yan College of Chemical Engineering and Materials Sciences, Zhejiang University of Technology, Hangzhou, Zhejiang, ChinaCorrespondence[email protected]
,
Zhongshi Zhou College of Biological and Environmental Sciences, Zhejiang Shuren University, Hangzhou, Zhejiang, China
&
Min Zhu College of Biological and Environmental Sciences, Zhejiang Shuren University, Hangzhou, Zhejiang, China
Pages 1495-1502 | Received 13 Sep 2005, Published online: 21 Aug 2006
 
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Abstract

The palladium chloride–catalyzed Suzuki coupling reaction of sodium tetraphenylborate with hypervalent iodonium salts and iodanes was achieved under microwave irradiation in water without base. A convenient and rapid method for formation of carbon–carbon bonds had excellent yields.

Acknowledgment

Financial support from the Zhejiang Province Natural Science Foundation of China (Project Y404016) and Zhejiang Province Education Foundation of China (Project 20040569) is greatly appreciated.

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