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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 12
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Original Articles

Zinc Hydroxyapatite–Catalyzed Efficient Synthesis of 5‐Substituted 1H‐Tetrazoles

, &
Pages 1809-1814 | Received 12 Sep 2005, Published online: 22 Aug 2006
 

Abstract

Zinc hydroxyapatite (ZnHAP) is an effective heterogeneous catalyst for the (2+3)‐cycloaddition of sodium azide with nitriles to afford 5‐substituted 1H‐tetrazoles in good yields. The catalyst is recovered and reused for several cycles with consistent activity.

Acknowledgment

We thank the CSIR for financial support under the Task Force Project CMM‐0006. K. B. Shiva Kumar thanks UGC, India, for the fellowship.

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