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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 15
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Original Articles

Synthesis and Spectroscopic Properties of a Covalently Linked Porphyrin–Fullerene C60 Dyad

M. Elisa Milanesio Department of Chemistry, University of Río Cuarto, Río Cuarto, Argentina
&
Edgardo N. Durantini Department of Chemistry, University of Río Cuarto, Río Cuarto, ArgentinaCorrespondence[email protected]
Pages 2135-2144 | Received 27 Jan 2006, Published online: 16 Feb 2007
 
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Abstract

A covalently linked porphyrin–fullerene C60 dyad 6 was conveniently synthesized by 1,3‐dipolar cycloaddition using 5‐(4‐carbonylphenyl)‐10,15,20‐tris(4‐methoxylphenyl)porphyrin 5, N‐methylglycine and fullerene C60. Spectroscopic studies show that dyad 6 is a promising architecture with potential application as photoactive organic material.

Acknowledgments

The authors are grateful to Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET) of Argentina, Agencia Nacional de Promoción Científica y Técnológica (FONCYT), and SECYT Universidad Nacional de Río Cuarto for financial support. E. N. D. is a scientific member of CONICET. M. E. M. thanks CONICET for a research fellowship.

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