Advanced search
Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 16
Submit an article Journal homepage
251
Views
15
CrossRef citations to date
0
Altmetric
Original Articles

Synthesis of Optically Pure Terminal Epoxide and 1,2‐Diol via Hydrolytic Kinetic Resolution Catalyzed by New Heterometallic Salen Complexes

Santosh Singh Thakur Department of Chemical Engineering, Inha University, Incheon, South Korea
,
Shu‐Wei Chen Department of Chemical Engineering, Inha University, Incheon, South Korea
,
Wenji Li Department of Chemical Engineering, Inha University, Incheon, South Korea
,
Chang‐Kyo Shin Department of Chemical Engineering, Inha University, Incheon, South Korea
,
Yoon‐Mo Koo Department of Biological Engineering, ERC for Advanced Bioseparation Technology, Inha University, Incheon, South Korea
&
Geon‐Joong Kim Department of Chemical Engineering, Inha University, Incheon, South KoreaCorrespondence[email protected]
Pages 2371-2383 | Received 13 Jan 2006, Published online: 22 Sep 2006
 
Sample our Physical Sciences journals, sign in here to start your FREE access for 14 days

Abstract

The inactive chiral (salen)Co complex is easily activated by InCl3 and TlCl3 Lewis acids by forming heterometallic salen complexes. These complexes show very high catalytic activity for the synthesis of enantiomerically enriched terminal epoxides (>99% ee) and 1,2‐diols simultaneously via hydrolytic kinetic resolution. Strong synergistic effects of different Lewis acids, Co‐In and Co‐Tl, were exhibited in the catalytic process. The system described is very simple and efficient.

Log in via your institution

Access through your institution

Log in to Taylor & Francis Online

Restore content access

Restore content access for purchases made as guest
Purchase options * Save for later

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.