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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 20
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Original Articles

ZnBr2‐Catalyzed Efficient Oxidative Homo Coupling of Aryl Magnesium BromidesFootnote

S. Ravi Kanth Fluoroorganic Division, Indian Institute of Chemical Technology, Hyderabad, India
,
G. Venkat Reddy Fluoroorganic Division, Indian Institute of Chemical Technology, Hyderabad, India
,
T. Yakaiah Fluoroorganic Division, Indian Institute of Chemical Technology, Hyderabad, India
,
B. Narsaiah Fluoroorganic Division, Indian Institute of Chemical Technology, Hyderabad, IndiaCorrespondence[email protected]
&
P. Shanthan Rao Fluoroorganic Division, Indian Institute of Chemical Technology, Hyderabad, India
Pages 3079-3084 | Received 09 Mar 2006, Published online: 16 Feb 2007
 
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Abstract

Oxidative homo coupling of various arylmagnesium bromides in the presence of ZnBr2 gave the corresponding symmetrical biaryls in moderate to good yields at room temperature. An efficient method under mild conditions without the use of reoxidant is described.

IICT Communication No. 050507

Acknowledgments

Authors thank J. S. Yadav, director, IICT, Hyderabad, and Shri S. Narayan Reddy, head, Fluoroorganic Division, IICT, for their constant encouragement. S. R. K. is grateful to Council of Scientific and Industrial Research (CSIR), New Delhi, for the grant of a senior research fellowship.

Notes

IICT Communication No. 050507

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