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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 17
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Original Articles

Facile and Efficient One‐Pot Protocol for the Synthesis of Benzoxazole and Benzothiazole Derivatives using Molecular Iodine as Catalyst

Firouz Matloubi Moghaddam Department of Chemistry, Sharif University of Technology, Tehran, IranCorrespondence[email protected]
,
Ghasem Rezanejade Bardajee Department of Chemistry, Sharif University of Technology, Tehran, Iran
,
Hossein Ismaili Department of Chemistry, Sharif University of Technology, Tehran, Iran
&
Seyedeh Maryam Dokht Taimoory Department of Chemistry, Sharif University of Technology, Tehran, Iran
Pages 2543-2548 | Received 16 Dec 2005, Published online: 27 Oct 2006
 
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Abstract

Rapid and efficient condensation reactions of 2‐aminothiophenol and 2‐aminophenol with various aldehydes were carried out using I2 in solvent‐free conditions with or without microwave irradiation to afford the corresponding 2‐substituted benzothiazole and benzoxazole derivatives in good to excellent yields.

Acknowledgment

We acknowledge the Islamic Development Bank (IDB) for granting the loan in 1993 for purchasing a 500‐MHz Bruker NMR spectrometer.

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