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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 21
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Original Articles

Effect of Substitution in Stannic Chloride–Mediated Heterocyclization of 4‐Allyl‐3‐hydroxyquinolin‐2(1H)‐ones

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Pages 3191-3201 | Received 13 Apr 2006, Published online: 24 Nov 2006
 

Abstract

Effect of substituents at the allylic position in a stannic chloride–iodine–mediated heterocyclization of 4‐allyl‐3‐hydroxyquinolin‐2(1H)‐ones for the regioselective formation of five‐ and six‐membered heterocyclic rings has been rationalized by the application of restricted Hatree–Fock calculation.

Acknowledgment

We thank the Council of Scientific and Industrial Research (CSIR) (New Delhi) for the financial assistance. N. Kundu is grateful to CSIR (New Delhi) for a junior research fellowship. We also thank Sandip Kar (Bhairab Ganguly College, Belgharia) for his help with the theoretical calculations.

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