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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 21
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Original Articles

Synthesis, Structures, and Properties of Novel N‐Aryl‐phenanthren‐o‐iminoquinones

Gleb A. Abakumov G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, Russia
,
Vladimir K. Cherkasov G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, Russia
,
Nikolai O. Druzhkov G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, Russia
,
Yury A. Kurskii G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, Russia
,
Georgii K. Fukin G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, Russia
,
Ludmila G. Abakumova G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, Russia
&
Tatiana N. Kocherova G.A. Rasuvaev Institute of Organometallic Chemistry RAS, Nizhniy Novgorod, RussiaCorrespondence[email protected]
 show all
Pages 3241-3247 | Received 04 Apr 2006, Published online: 24 Nov 2006
 
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Abstract

The interaction of 9,10‐phenanthrenquinone with primary amines has been studied. Use of sterically hindered anilines gave the phenanthren‐o‐iminoquinones in good yields. These compounds are structural analogues of o‐benzoquinones. Using single‐electron reduction, o‐iminoquinones may synthesize metal's free‐radical complexes.

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