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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 21
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Original Articles

Synthesis of Ketones from Acyl Chlorides and Triorganoindium Reagents by Pd‐Catalyzed Cross‐Coupling

C. Croix CEA Le Ripault, Materials Department, Monts, France
,
A. Balland‐Longeau CEA Le Ripault, Materials Department, Monts, France
,
A. Duchêne Laboratoire de Synthèse et Physicochimie Organique et Thérapeutique, Faculté des Sciences de Tours, Parc de Grandmont, Tours, France
&
J. Thibonnet Laboratoire de Synthèse et Physicochimie Organique et Thérapeutique, Faculté des Sciences de Tours, Parc de Grandmont, Tours, FranceCorrespondence[email protected]
Pages 3261-3270 | Received 04 Apr 2006, Published online: 24 Nov 2006
 
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Abstract

Triorganoindium reagents prepared from indium tribromide and 3 equiv of organolithium reagents react with acyl chlorides in palladium‐catalyzed cross‐coupling for preparation of new ketones.

Acknowledgments

We thank CEA Le Ripault for providing financial support and characterization.

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