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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 36, 2006 - Issue 24
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Original Articles

New Method for the Synthesis of 2‐Aza‐1,3‐Butadienes

Pages 3693-3702 | Received 11 Dec 2005, Published online: 01 Dec 2006
 

Abstract

2‐Aza‐1,3‐butadienes have been synthesized from carbonyl compounds and 1,1,1,3,3,3‐hexamethyl‐disilazane in the presence of cobalt‐containing catalysts. The best yields (up to 95%) were achieved in the case of aldehydes branched in the α-position and 2-methylcyclohexanone. In the case of two α,β‐unsaturated ketones, pyridine derivatives were found as the main products.

Acknowledgment

The authors acknowledge helpful discussion with F. Ungváry, G. Szalontai, and B. Szabo, technical assistance of E. Fekete and E. Klujber, and financial support from the Hungarian Academy of Sciences (Grant No. OTKA T031934).

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