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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 7
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Original Articles

Solvent‐Free Chemoselective Synthesis of 1,1‐Diacetates Catalyzed by Cu(NO3)2 · 3H2O

Majid M. Heravi Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, IranCorrespondence[email protected]
,
Khadijeh Bakhtiari Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran
,
Maryam H. Tehrani Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran
&
Hossein A. Oskooie Department of Chemistry, School of Sciences, Azzahra University, Vanak, Tehran, Iran
Pages 1121-1126 | Received 06 Jun 2006, Published online: 13 Oct 2010
 
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Abstract

1,1‐Diacetates have been synthesized by the reaction of a variety of aldehydes with acetic anhydride in the presence of cupric nitrate as catalyst under solvent‐free conditions. Ketones were not converted to the corresponding diacetates under these conditions.

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