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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 7
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Original Articles

Synthesis of Functionalized 1‐Azadienes by Reaction of 2,6‐Dimethylphenyl Isocyanide and Acetylenic Esters in the Presence of CH Acids

Issa Yavari Department of Chemistry, Tarbiat Modarres University, Tehran, IranCorrespondence[email protected]
&
Elham Karimi Department of Chemistry, Tarbiat Modarres University, Tehran, Iran
Pages 1189-1194 | Received 27 Jun 2006, Published online: 13 Oct 2010
 
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Abstract

The adducts produced in the reaction between 2,6‐dimethylphenyl isocyanide and acetylenic esters were trapped by 3‐chloroacetylacetone, dialkyl 2‐chloromalonates, or dimethoxy methoxymalonate to produce highly functionalized 1‐azadienes in good yields.

Acknowledgment

This work was supported by the Presidential Office for Research through Grant No. 83123.

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