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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 37, 2007 - Issue 16
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Original Articles

Nitration of Some Aromatic Compounds by Sodium Nitrate in the Presence of Benzyltriphenylphosphonium Peroxodisulfate

Hassan Tajik Department of Chemistry, Guilan University, Guilan, Iran; Persian Gulf University, Bushehr, Iran
,
Mohammad Ali Zolfigol College of Chemistry, Bu Ali Sina University, Hamadan, Iran
,
Jalal Albadi Department of Chemistry, Guilan University, Guilan, Iran; Persian Gulf University, Bushehr, Iran
&
Ramin Eslami Department of Chemistry, Guilan University, Guilan, Iran; Persian Gulf University, Bushehr, Iran
Pages 2771-2776 | Received 04 Aug 2006, Published online: 14 Aug 2007
 
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Abstract

A simple, mild, and regioselective method for the nitration of some aromatic compounds using sodium nitrate in the presence of benzyltriphenylphosphonium peroxodisulfate in acetonitrile as solvent is reported. Mild reaction conditions and good to excellent yields of the products are the noteworthy advantages of the method.

Acknowledgment

We are thankful to Guilan University and University of Persian Gulf Research Council for the partial support of this work.

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