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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 3
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Original Articles

Reaction between Imides and Electron‐Poor Acetylenic Esters in the Presence of Dipotassium Hydrogen Phosphate Powder in Solvent‐Free Conditions: An Efficient Method for the Synthesis of Electron‐Poor N‐Vinyl Imides

Ali Ramazani Department of Chemistry, University of Zanjan, Zanjan, IranCorrespondence[email protected]
,
Mahsa Kardan Department of Chemistry, University of Zanjan, Zanjan, Iran
&
Nader Noshiranzadeh Department of Chemistry, University of Zanjan, Zanjan, Iran
Pages 383-390 | Received 04 Apr 2007, Published online: 28 Jan 2008
 
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Abstract

A two‐component condensation reaction between an imide and an electron‐poor acetylenic ester efficiently provides substituted electron‐poor N‐vinyl imides in a one‐pot reaction in the presence of dipotassium hydrogen phosphate powder in solvent‐free conditions. The reaction is fairly stereoselective.

Acknowledgment

This work was supported by the Sandoogh Hemayate as Pajuoheshgharane Keshvare Iran.

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