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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 16
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Original Articles

Synthesis of Ethyl Nicotinate-5-Boronic Acid Pinacol Ester and Its Application Toward Suzuki Coupling

Yves Leblanc Merck Frosst Centre for Therapeutic Research, Québec, Canada
&
Pascal Cérat Merck Frosst Centre for Therapeutic Research, Québec, Canada
Pages 2775-2781 | Received 31 Jul 2008, Accepted 18 Oct 2007, Published online: 25 Aug 2010
 
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Abstract

A method for the synthesis and isolation of pure ethyl nicotinate-5-boronic acid pinacol ester has been described. This boronate ester was used to prepare C2-C5 heteroarylnicotinates in good yields.

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