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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 8
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Original Articles

Hydrolytic Kinetic Resolution of Terminal Epoxides catalyzed by Novel Bimetallic Chiral Co (Salen) Complexes

Rahul B. Kawthekar Department of Chemical Engineering, Inha University, Incheon, South Korea
&
Geon‐Joong Kim Department of Chemical Engineering, Inha University, Incheon, South KoreaCorrespondence[email protected]
Pages 1236-1248 | Published online: 17 Apr 2008
 
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Abstract

Novel bimetallic chiral Co (salen) complexes bearing transition‐metal salts have been synthesized. The easily prepared complexes exhibited very high catalytic reactivity and enantioselectivity in hydrolytic kinetic resolution (HKR) of racemic terminal epoxides and consequently provided enantiomerically enriched epoxides (up to 99% ee).

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