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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 10
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Original Articles

[α‐PW12O40]3− Immobilized on Ionic Liquid–Modified Polymer as a Heterogeneous Catalyst for Alcohol Oxidation with Hydrogen Peroxide

Xianjun Lang State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China; Graduate University of Chinese Academy of Sciences, Beijing, China
,
Zhen Li State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China
&
Chungu Xia State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, ChinaCorrespondence[email protected]
Pages 1610-1616 | Received 05 Nov 2007, Published online: 24 Apr 2008
 
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Abstract

Ionic liquid–modified polystyrene resin beads were demonstrated to be an appropriate support for polyoxometalate. In this heterogeneous catalytic system, alcohols can be efficiently oxidized to corresponding carbonyl groups with H2O2 in CH3CN. The catalyst can be easily recovered by filtration and recycled without apparent loss of catalytic performance.

Acknowledgment

This work is financially supported by the National Natural Science Foundation of China (No. 20373082) and National Science Fund for Distinguished Young Scholars (No. 20625308).

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