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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 38, 2008 - Issue 23
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Original Articles

Synthesis of Optically Active 1,4-Dioxane Nucleotide Analogs

, &
Pages 4250-4264 | Received 27 Mar 2008, Published online: 31 Oct 2008
 

Abstract

Optically active nucleotide analogs were prepared that were composed of a 1,4-dioxane ring as the sugar analog to which either uracil or adenine attached together with two carboxylic ester groups, to be used as vehicles for formation of oligomers. The chiral 1,4-dioxane moiety was constructed from dimethyl L-tartrate via the corresponding (2R,3R)-dimethyl 2-O-allyl-tartrate.

ACKNOWLEDGMENTS

We thank the Norwegian Research Council for generous financial support.

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