Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 39, 2008 - Issue 2
88
Views
4
CrossRef citations to date
0
Altmetric
Original Articles

Potassium Dodecatungsto Cobaltate Trihydrate: A New Heterogeneous Catalyst for the Synthesis of Homoallylic Alcohols and Amines

, , , &
Pages 355-365 | Received 21 Apr 2008, Published online: 22 Dec 2008
 

Abstract

A simple and efficient procedure has been developed for one-pot synthesis of homoallylic alcohols and amines in good to excellent yields using a variety of aldehydes, amines, and allyltributylstannane in the presence of a catalytic amount of potassium dodecatungsto cobaltate trihydrate (K5CoW12O40 · 3H2O) as a heterogeneous catalyst at room temperature. The catalyst exhibited remarkable reusability.

ACKNOWLEDGMENT

S. A. thanks Council of Scientific and Industrial Research, New Delhi, for financial assistance, and authors thank the head, Organic Chemistry Division II, and director, Indian Institute of Chemical Technology, Hyderabad, for their constant encouragement and support.

Notes

a All products were characterized by 1H NMR, 13C NMR, IR, and mass spectroscopy.

b Isolated and unoptimized yields.

a All products were characterized by 1H NMR, 13C NMR, IR, and mass spectroscopy.

b Isolated and unoptimized yields.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.