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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 39, 2009 - Issue 3
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Original Articles

Novel One-Pot Procedure for the Synthesis of 1,2-Diketones

Xiaobi Jing College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, ChinaCorrespondence[email protected]
,
Xin Pan College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, China
,
Zhen Li College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, China
,
Yaocheng Shi College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, China
&
Chaoguo Yan College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, China
Pages 492-496 | Received 10 May 2008, Published online: 08 Jan 2009
 
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Abstract

A simple and convenient one-pot procedure is reported for the synthesis of 1,2-diketones from corresponding benzoin-type condensation reaction of aromatic aldehydes in water with N,N-dialkylbenzimidazolium salt as condensation catalyst and ferric chloride as oxidizing reagent.

ACKNOWLEDGMENTS

This research was supported by the National Natural Science Foundation of China (20572091 20576111) and the Cultivation and Construction Fund for the State Key Subject of Physical Chemistry.

Notes

aIsolated yields

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