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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 40, 2010 - Issue 16
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Original Articles

Mild Oxidative Conversion of Nitroalkanes into Carbonyl Compounds in Ionic Liquids

, , , &
Pages 2483-2487 | Received 03 Aug 2009, Published online: 26 Jul 2010
 

Abstract

Basic hydrogen peroxide and sodium perborate were found to be cheap and efficient alternatives for the conversion of primary and secondary nitro to carbonyl compounds (Nef reaction) in ionic liquids.

ACKNOWLEDGMENT

The authors are grateful to the University of Calabria for financial support.

Notes

a Determined by GC.

b Isolated yield.

c Room temperature.

d 70 °C.

a Both conversion and yield were determined by GC analysis.

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