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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 40, 2010 - Issue 21
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Original Articles

Easy Access to α-Bromoketones and Epoxides from vic-Dibromides Under Aqueous Conditions

Rajendra D. Patil Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, Bhavnagar, Gujarat, India
,
Subbarayappa Adimurthy Central Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, Bhavnagar, Gujarat, IndiaCorrespondence[email protected]
&
Brindaban C. Ranu Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata, IndiaCorrespondence[email protected]
Pages 3233-3239 | Received 03 Aug 2009, Published online: 04 Oct 2010
 
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Abstract

The conversion of vic-1,2 dibromides to α-bromoketones and epoxides using H2O2/dioxane and NaOH/water respectively under mild conditions has been described.

ACKNOWLEDGMENT

The authors gratefully acknowledge the Department of Science and Technology, New Delhi, India, for the financial support of this project under the Green Chemistry Task Force, Scheme No. SR/S5/GC-02A/2006.

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