Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 40, 2010 - Issue 24
729
Views
4
CrossRef citations to date
0
Altmetric
Original Articles

Nitration of Aromatic Hydrocarbons and Halobenzenes Using NOx Catalyzed by Solid Acid Catalysts

&
Pages 3734-3738 | Received 28 Aug 2009, Published online: 09 Nov 2010
 

Abstract

The nitration of aromatics using zeolite as a solid inorganic catalyst and nitric oxides as nitrating agents is a relatively clean process for aromatic nitration.

ACKNOWLEDGMENT

Financial support by the Government of India under “Technical Education Quality Improvement Programme” (TEQIP) is gratefully acknowledged.

Notes

Reaction conditions: Chlorobenzene (30 mmol), catalyst zeolite Hβ, 1,2-dichloroethane (30 ml), HNO3 4 ml, P2O5 10 g; temperature 40 °C, reaction time 240 min.

a GC.

Reaction conditions: Chlorobenzene (30 mmol), catalyst 1 wt% wrt wt. of CB, dichloroethane (30 ml), HNO3 4 ml, P2O5 10 g; temperature 40 °C, reaction time 240 min.

a GC.

Reaction conditions: substrate (30 mmol), catalyst zeolite Hβ 1 wt% wrt wt. of substrate, dichloroethane (30 mL), HNO3 4 ml, P2O5 10 g; temperature 40 °C, reaction time 240 min.

a Without catalyst.

b GC and GC-MS.

c Exclusive 1-nitronaphthalene.

d 2,3-Dichloro-1-nitrobenzene.

e 3,4-Dichloro-1-nitrobenzene.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.