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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 41, 2011 - Issue 3
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Original Articles

Facile and Efficient Michael Addition of Indole to Nitroolefins Catalyzed by Zn(OAc)2 · 2H2O

, &
Pages 372-379 | Received 10 Aug 2009, Published online: 13 Jan 2011
 

Abstract

The Zn(OAc)22H2O-catalyed Michael addition reaction of indole to electron-deficient nitroolefins to afford the corresponding adducts in good to excellent yields with high selectivity is reported.

ACKNOWLEDGMENTS

We are grateful for support from the National Natural Science Foundation of China (20702043), the Jiangsu Provincial Natural Science Foundation (BK2006549), and the Program for New Century Excellent Talents in Yangzhou University.

Notes

a Conditions: 1 (0.3 mmol), 2a (0.36 mmol), and solvent (2 mL).

b Yield after column chromatography.

a Conditions: 1 (0.3 mmol), 2a–i (0.36 mmol), and solvent (2 mL).

b Yield after column chromatography.

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