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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 41, 2011 - Issue 18
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Original Articles

Direct and Selective Conversion of Benzyl Bromides to Benzaldehydes with Aqueous H2O2 Without Catalyst

Rajendra D. PatilCentral Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, Bhavnagar, Gujarat, India
&
Subbarayappa AdimurthyCentral Salt and Marine Chemicals Research Institute, Council of Scientific and Industrial Research, Bhavnagar, Gujarat, India
Pages 2712-2718 | Received 07 Apr 2010, Published online: 29 Jun 2011
 
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Abstract

The facile and selective conversion of benzylic bromides to benzaldehydes using H2O2 as a benign oxidizing agent in an aqueous medium is described. Under these conditions, good yields of benzaldehydes were obtained.

Graphical Abstract

ACKNOWLEDGMENT

R. D. Patil is thankful to the Council of Scientific and Industrial Research, New Delhi, India, for his senior research fellowship award.

Notes

aIsolated yields.

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