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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 42, 2012 - Issue 24
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Original Articles

Design and Synthesis of Dumbbell-Shaped POSS-C60 Dyads with Flexible Spacer

Fafu Yang College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, China; Fujian Key Laboratory of Polymer Materials, Fuzhou, ChinaCorrespondence[email protected]
,
Congcong Li College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, China
,
Hongyu Guo College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, China
,
Jinqi Ye College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, China
&
Ziyu Jiao College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, China
Pages 3664-3669 | Received 27 Mar 2011, Published online: 20 Aug 2012
 
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Abstract

Using polyhedral oligomeric silsesquioxane (POSS) as starting material, novel dumbbell-shaped POSS-C60 dyads with flexible spacers were designed and synthesized in good yields by esterification, subsequent etherification, and further 1,3-dipolar cycloaddition of azomethine ylide generated in situ from aldehyde and sarcosine to C60.

GRAPHICAL ABSTRACT

ACKNOWLEDGMENTS

Financial support from the National Natural Science Foundation of China (No. 20402002), Fujian Natural Science Foundation of China (No. 2009J01019), and Program for Excellent Young Researchers in University of Fujian Province (JA10056) were greatly acknowledged. Thanks go to Prof. Lei Zhu at Case Western Reserve University for supplying the materials.

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