Publication Cover
Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 43, 2013 - Issue 3
206
Views
1
CrossRef citations to date
0
Altmetric
Original Articles

Pyrolysis of Calcium Salt of Alkoxybenzoic Acids Fails to Produce Diarylketones: An Unusual Observation

, &
Pages 384-391 | Received 11 Mar 2011, Published online: 02 Nov 2012
 

Abstract

Pyrolysis of calcium salt of alkoxybenzoic acid leads to the formation of alkoxybenzoic ester instead of alkoxy benzophenone.

GRAPHICAL ABSTRACT

ACKNOWLEDGMENT

We are grateful to the Council of Scientific and Industrial Research (CSIR) for providing a SRF-NET fellowship to K. S.

Notes

a Yield was calculated based on 2 equivalents of calcium salt producing 1 equivalent of esters. All the compounds are known compounds and the spectroscopic data [infrared (IR), 1H NMR, and 13C NMR] of the synthesized compounds are in good agreement with the literature reports.[ Citation 4 Citation 5 Citation 6 Citation 7 Citation 8 Citation 9 Citation 10 Citation 11 Citation 12 Citation 13 Citation 14 Citation 15 Citation 16 ] Thin-layer chromatography (TLC) of the synthesized compounds was also identical with the authenticated samples. To the best of our knowledge, such surprising observations have not been reported in the literature prior to this study.

Log in via your institution

Log in to Taylor & Francis Online

PDF download + Online access

  • 48 hours access to article PDF & online version
  • Article PDF can be downloaded
  • Article PDF can be printed
USD 61.00 Add to cart

Issue Purchase

  • 30 days online access to complete issue
  • Article PDFs can be downloaded
  • Article PDFs can be printed
USD 422.00 Add to cart

* Local tax will be added as applicable

Related Research

People also read lists articles that other readers of this article have read.

Recommended articles lists articles that we recommend and is powered by our AI driven recommendation engine.

Cited by lists all citing articles based on Crossref citations.
Articles with the Crossref icon will open in a new tab.