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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 45, 2015 - Issue 1
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Original Articles

Synthesis and Metal Complex Formation of a Bis(terpyridine) Derivative with a Phenylacetylene Framework

Tomoyuki Tokizaki Department of Biomolecular Science, Faculty of Science, Toho University, Chiba, Japan
,
Takuya Toyoshima Department of Biomolecular Science, Faculty of Science, Toho University, Chiba, Japan; Research Center for Materials with Integrated Properties, Toho University, Chiba, Japan
&
Soichiro Watanabe Department of Biomolecular Science, Faculty of Science, Toho University, Chiba, Japan; Research Center for Materials with Integrated Properties, Toho University, Chiba, JapanCorrespondence[email protected]
Pages 127-136 | Received 08 Apr 2014, Published online: 19 Nov 2014
 
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Abstract

A new bis(terpyridine) derivative with a phenylacetylene framework was synthesized via a stepwise terpyridine construction strategy. The addition of ZnCl2 to a solution of the bis(terpyridine) in chloroform resulted in UV/vis and 1H NMR spectral changes because of complex formation.

GRAPHICAL ABSTRACT

Notes

Dedicated to Prof. Renji Okazaki on the occasion of his 77th birthday.

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