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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 45, 2015 - Issue 3
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Original Articles

Sodium Perborate: A Facile Catalyst for Allylation of Active Centers

, , , &
Pages 355-362 | Received 26 Jun 2014, Published online: 13 Dec 2014
 

GRAPHICAL ABSTRACT

Abstract

An efficient and ecofriendly allylation of O-H, N-H, and C-H groups has been achieved successfully with the reaction of allyl bromide by using sodium perborate as a new catalyst in aqueous media. The advantage of this method is operationally simple, short reaction time, good yield, and simple workup conditions over the previously reported conventional methods such as amination, oxyalkylation reactions of allyl bromide, and Friedel–Crafts allylation chemistry.

ACKNOWLEDGMENTS

We thank Professor C. D. Reddy, Department of Chemistry, Sri Venkateswara University, Tirupati, for his helpful discussions. We state that none of the authors have any conflict of interest in the context of this communication.

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