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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 45, 2015 - Issue 6
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Original Articles

Graphene Oxide as Recyclable Catalyst for One-Pot Synthesis of α-Aminophosphonates

, , &
Pages 778-788 | Received 17 Oct 2014, Published online: 14 Jan 2015
 

Abstract

We report the synthesis of α-aminophosphonates from aromatic aldehydes, aromatic and aliphatic amines, and trimethylphosphite (Kabachnik–Fields reaction) using a “carbocatalyst,” graphene oxide, at room temperature with excellent yield and recyclability. Enhanced catalytic activity of graphene oxide as compared to other catalysts studied is possibly due to the presence of carboxylic acid and hydroxyl groups.

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