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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 45, 2015 - Issue 12
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Original Articles

Iodine Monochloride (ICl) as a Highly Efficient, Green Oxidant for the Oxidation of Alcohols to Corresponding Carbonyl Compounds

Peng WeiSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China
,
Datong ZhangSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, ChinaCorrespondence[email protected]
,
Zhigang GaoSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China
,
Wenqing CaiTianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China
,
Weiren XuTianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China
,
Lida TangTianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, China
&
Guilong ZhaoSchool of Chemistry and Pharmaceutical Engineering, Qilu University of Technology, Jinan, China;Tianjin Key Laboratory of Molecular Design and Drug Discovery, Tianjin Institute of Pharmaceutical Research, Tianjin, ChinaCorrespondence[email protected]
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Pages 1457-1470 | Received 16 Sep 2014, Published online: 05 May 2015
 
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ABSTRACT

Iodine monochloride (ICl) was discovered to be a highly efficient, green oxidant, which can oxidize aldose hemiacetals, diarylmethanols, arylalkylmethanols, anddialkylmethanols to the corresponding aldose lactones, diarylmethanones, arylalkylmethanones, and dialkylmethanones, respectively, in high yields. ICl as a green, metal-free oxidant is characterized by mild reaction condition, short reaction time, good yield, and broad scope.

GRAPHICAL ABSTRACT

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