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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 48, 2018 - Issue 6
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Original Articles

Synthesis of 3-(quinolin-2-yl)indolizines through iodine-mediated sp3C–H functionalization of azaarenes

Issa YavariDepartment of Chemistry, Tarbiat Modares University, Tehran, IranCorrespondence[email protected]
&
Maryam NaeimabadiDepartment of Chemistry, Tarbiat Modares University, Tehran, Iran
Pages 632-637 | Received 11 Mar 2017, Published online: 21 Feb 2018
 
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ABSTRACT

An efficient approach toward C–H bond activation using iodine-mediated sp3C–H bond functionalization for the synthesis of dialkyl 3-(quinolin-2-yl)indolizine-1,2-dicarboxylates and dialkyl 3-(quinolin-2-yl)pyrrolo[2,1-a]isoquinoline-1,2-dicarboxylates through 1,3-dipolar cycloaddition reaction of nitrogen ylides with acetylenic esters is described.

GRAPHICAL ABSTRACT

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