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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 48, 2018 - Issue 9
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Original Articles

House bulb light-induced photochemical acetalization of carbonyl compounds catalyzed by Eosin Y

Quan ZhouSchool of Chemistry and Chemical Engineering, Huangshan College, Huangshan, P. R. ChinaView further author information
,
Tao JiaAnhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, P. R. ChinaView further author information
,
Xiao-Xuan LiAnhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, P. R. ChinaView further author information
,
Lin ZhouTongcheng Teachers College, Tongcheng, Anhui, P. R. ChinaView further author information
,
Chang-Jiang LiSchool of Chemistry and Chemical Engineering, Huangshan College, Huangshan, P. R. ChinaView further author information
&
Yi-Si FengAnhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, School of Chemistry and Chemical Engineering, Hefei University of Technology, Hefei, P. R. China;Anhui Provincial Laboratory of Heterocyclic Chemistry, Maanshan, Anhui, P. R. ChinaCorrespondence[email protected]
View further author information
Pages 1068-1075 | Received 04 Nov 2017, Published online: 07 May 2018
 
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ABSTRACT

We have systematically studied the reactions of acetalization and found that high reaction efficiency can be achieved using cheap and readily available organic Eosin Y as catalyst. The reaction proceeds smoothly under house bulbs and shows excellent functional group tolerance. The substrates of the reaction system are compatible with aromatic aldehydes, aliphatic aldehydes, aromatic ketones, and cyclic ketones with high yields.

GRAPHICAL ABSTRACT

Additional information

Funding

We gratefully acknowledge the financial assistance from the National Natural Science Foundation of China (Nos. 21371044, 21571047) and the Natural Science Foundation of Anhui Province (No. KJ2016A701).

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