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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 48, 2018 - Issue 14
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Synthetic Communications Review

N-heterocyclic carbene-catalyzed regio- and stereoselective hydrothiolation reaction of alkynes

Zi-Song CongLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information
,
Yang ZhangLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information
,
Guang-Fen DuLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaCorrespondence[email protected]
View further author information
,
Cheng-Zhi GuLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information
&
Lin HeLaboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, School of Chemistry and Chemical Engineering, Shihezi University, Xinjiang Uygur, Autonomous Region, People’s Republic of ChinaView further author information
Pages 1838-1846 | Received 08 Jan 2018, Published online: 18 Jun 2018
 
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Abstract

N-heterocyclic carbenes (NHCs) have been utilized as Brønsted base to catalyze the hydrothiolation reaction between alkynes and thiols to produce the vinyl sulfides stereoselectively.

Graphical Abstract

Graphical Abstract

Additional information

Funding

This work was supported by the National Natural Science Foundation of China [No. 21662029], the Young Scientists Foundation of Shihezi University [Nos. RCZX201546, 2015ZRKXJQ05] and the Excellent Young Teachers Plan of Bingtuan [CZ027203].

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