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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 49, 2019 - Issue 23
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SYNTHETIC COMMUNICATIONS REVIEWS

Recent advances in C–S bond construction to synthesize sulfone

Yaqiong LiSchool of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing, P. R. China; Correspondence[email protected]
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Yuhang FanSchool of Chemistry and Chemical Engineering, Yangtze Normal University, Chongqing, P. R. China; ;State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, P. R. ChinaView further author information
Pages 3227-3264 | Received 09 Jun 2019, Published online: 13 Sep 2019
 
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Abstract

Sulfone is prevalent in natural products and has been widely used in organic chemistry. Among the approaches of installing sulfonyl group, sulfonylation starting from stable and environmentally friendly sulfonyl sources is promising and attractive. Diverse mild sulfonyl sources such as DABSO, inorganic metal salts, sulfinic acids/salts, and sulfonyl hydrazides have been applied to construct sulfone. In this review, recent advances for the sulfonylation under transition metal catalysis and metal-free conditions are summarized.

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Funding

Project supported by the Science Foundation of Yangtze Normal University [No. 2017KYQD24].

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