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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 50, 2020 - Issue 7
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ARTICLES

Synthesis of aryl allyl alkynes via reaction with allyl amine and aryl alkynoic acids through decarboxylation

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Pages 1008-1015 | Received 28 Dec 2019, Published online: 26 Feb 2020
 

Abstract

Allyl alkynoic esters were synthesized by the reaction of allyl amines and alkynoic acids via deaminative esterification. The reaction of allyl alkynoic esters with Pd(dba)2 and Xantphos in digylme at 110 °C for 12 h afforded the desired decarboxylated allyl alkynes in good yields.

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Disclosure statement

No potential conflict of interest was reported by the author(s).

Additional information

Funding

This work was supported by the National Research Foundation of Korea (NRF) and funded by the Korea Government (MSIP) [grant number NRF-2017R1D1A3B03035736], [grant number NRF-2015R1A4A1041036]. The spectral data were obtained from the Korea Basic Science Institute, Gwangju branch.

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