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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 50, 2020 - Issue 15
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Articles

Dichlorination of olefins with diphenyl sulfoxide/oxalyl chloride

Rui DingBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, ChinaView further author information
,
Shuai HuangBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, ChinaView further author information
,
Qiyi WangBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, ChinaView further author information
,
Yongguo LiuBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, ChinaView further author information
,
Baoguo SunBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, ChinaView further author information
&
Hongyu TianBeijing Advanced Innovation Center for Food Nutrition and Human Health, Beijing Key Laboratory of Flavor Chemistry, Beijing Technology and Business University, Beijing, ChinaCorrespondence[email protected]
View further author information
Pages 2319-2330 | Received 03 Dec 2019, Published online: 05 Jun 2020
 
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Abstract

The combination of diphenyl sulfoxide and oxalyl chloride was used to accomplish the dichlorination of olefins, in which chlorodiphenylsulfonium salt generated in situ was proposed to be the real active species as a chloronium ion source.

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Additional information

Funding

Financial support from the National Key Research and Development Program [2016YFD0400801].

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