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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 50, 2020 - Issue 17
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Articles

Sunlight assisted solvent free synthesis of tert-butylperesters

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Pages 2698-2703 | Received 20 May 2020, Published online: 12 Jul 2020
 

Abstract

A green and efficient methodology has been developed for the direct conversion of aryl aldehydes to the corresponding tert-butyl peresters. The reaction has been carried out in absence of any solvent and the sunlight is used as the green source of energy. In this reaction tetrabutylammonium iodide (TBAI) acts as the mild organo catalyst and tert-butyl hydroperoxide (TBHP) serve as the source of tert-butyl group.

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Funding

I would like to thank DST-SERB, Government of India for financial support of this project [File No.: ECR/2017/000396] and DST-FIST, Government of India for sponsoring departmental research facilities.

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