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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 3, 1973 - Issue 5
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Original Articles

A General Synthesis of α-Substituted Acrylic Esters

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Pages 359-363 | Received 21 Aug 1973, Published online: 05 Dec 2006
 

Abstract

During a study of synthetic approaches to various naturally-occurring sesquiterpenes lactones, we developed a new synthesis of the α-methylene-γ-butyrolactone group.1 This new sequence suggested that it might be applicable to the general synthesis of α-methylenecarbonyl compounds.2 This report describes the application to a general synthesis of α-substituted acrylic esters.

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