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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 7, 1977 - Issue 4
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Original Articles

The Preparation and Reactions of Anions of Certain Schiff Bases

Steven E. Davis Department of Chemistry, Newberry College, Newberry, S. C., 29108
,
Lynn M. Schaffer Department of Chemistry, Newberry College, Newberry, S. C., 29108
,
Neal L. Shealy Department of Chemistry, Newberry College, Newberry, S. C., 29108
,
Keith D. Shealy Department of Chemistry, Newberry College, Newberry, S. C., 29108
&
Charles F. Beam Department of Chemistry, Newberry College, Newberry, S. C., 29108
Pages 261-268 | Received 03 Mar 1977, Published online: 23 Oct 2006
 
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Abstract

We have recently reported the facile preparation of C(α)-multiple anions of oximes2, phenylhydrazones3, hydraxones4, and acylhydrazones5. In each case the C(α)-carbanion reacted with electrophilic reagents such as aromatic esters, an alphatic diester6, acid chlorides7, aldehydes8, ketones9, carbon dioxide10, and nitriles11 (Scheme I).

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