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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 14, 1984 - Issue 8
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Original Articles

Synthesis of α,β Unsaturated Esters Using a Solid-Liquid Phase Transfer in a Slightly Hydrated Aprotic Medium

Zéphirin Mouloungui Laboratoire de Chimie Organique et d'Agrochimie Ecole Nationale Supérieure de Chimie, I.N.P., 118, route de Narbonne, 31077, TOULOUSE Cedex, France
,
Michel Delmas Laboratoire de Chimie Organique et d'Agrochimie Ecole Nationale Supérieure de Chimie, I.N.P., 118, route de Narbonne, 31077, TOULOUSE Cedex, France
&
Antoine Gaset Laboratoire de Chimie Organique et d'Agrochimie Ecole Nationale Supérieure de Chimie, I.N.P., 118, route de Narbonne, 31077, TOULOUSE Cedex, France
Pages 701-706 | Published online: 06 Dec 2006
 
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Abstract

The condensation reaction of alkylphosphonates with variously functionnalysed aldehydes in the presence of solid potassium carbonate in low hydrated aprotic media leads to the selective formation of αβ-unsaturated esters E in high yields.

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