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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 15, 1985 - Issue 1
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Original Articles

The Reaction of Activated Aryl and Heteroaryl Dihalides with Hmpa. A Regioselectivity Study

John T. Gupton Department of Chemistry, University of Central Florida, Orlando, FL, 32816
,
Ernest Wysong Department of Chemistry, University of Central Florida, Orlando, FL, 32816
,
Bryan Norman Department of Chemistry, University of Central Florida, Orlando, FL, 32816
,
George Hertel Department of Chemistry, University of Central Florida, Orlando, FL, 32816
&
John P. Idoux Department of Chemistry, Lamar University, Beaumont, TX, 77710
Pages 43-52 | Published online: 05 Dec 2006
 
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Abstract

A series of activated aryl and heteroaryl dihalides were reacted with HMPA at elevated temperatures. Of the eleven examples studied, all but one reacted in a regioselective manner to give a monohalo-N,N-dimethylamino derivative.

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