On the Ketene Alkylsilyl Acetal Preparations: Synthetic Communications: Vol 17, No 1

Synthetic Communications

An International Journal for Rapid Communication of Synthetic Organic Chemistry

Volume 17, 1987 - Issue 1

228

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Abstract

The action of zinc powder with α-bromoesters in the presence of trimethylsilylchloride and TMEDA-Et3N led mainly to E-ketenealkyl-silylacetals while the reaction of trialkylsilanes on alkyl acrylates catalyzed by Wilkinson reagent gave stereoselectively the Z isomers.

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On the Ketene Alkylsilyl Acetal Preparations

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On the Ketene Alkylsilyl Acetal Preparations

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