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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 18, 1988 - Issue 10
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Original Articles

Synthetic Utility of α-Stannyl α,β-Unsaturated Esters as Reagents for β-Substituted Acrylate α-Anion Synthons: Tin-Lithium Exchange and Palladium-Catalized Coupling Reactions

Acuña A. Carola Departamento de Química, Universidad Simón Bolívar, Apartado Postal 89000, Caracas, 1080-A, Venezuela
&
Antonio Zapata Departamento de Química, Universidad Simón Bolívar, Apartado Postal 89000, Caracas, 1080-A, Venezuela
Pages 1125-1131 | Published online: 06 Dec 2006
 
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Abstract

The tin-lithium exchange and the palladium-catalized coupling reactions of the title compounds have been studied. The latter reaction was found to be more efficient for functionalizing the α-carbon of these esters.

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