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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 1-2
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Original Articles

A Facile Approach to 20-Isocholesterol From An Androstane Derivative

A. Jarzebski Institute of Oceanology, Polish Academy of Sciences, Powstańców Warszawy 55, 81-967, Sopot, Poland
&
J. Wicha Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44, 01-224, Warszawa, Poland
Pages 63-70 | Received 01 Jun 1988, Published online: 24 Oct 2006
 
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Abstract

A high-yield stereoselective synthesis of (20S)-cholest-5-en-3ß-ol from 3ß-(tetrahydropyran-2-yloxy)-androst-5-en-17-one via ethyl (20R)-3ß-(tetrahydropyran-2-yloxy)-23, 24-bisnorchol-5-en-22-oate is described.

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