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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 19, 1989 - Issue 13-14
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Original Articles

Preparation of Isomerically Pure Alkylaminfs via the Reaction of Dimethylalkylboranes with Chloramine

George W. Kabalka Departments of Chemistry and Radiology, University of Tennessee, Knoxville, TN, 37996-1600
,
Zhe Wang Departments of Chemistry and Radiology, University of Tennessee, Knoxville, TN, 37996-1600
&
Naganna H. Goudgaon Departments of Chemistry and Radiology, University of Tennessee, Knoxville, TN, 37996-1600
Pages 2409-2414 | Received 20 Feb 1989, Published online: 24 Oct 2006
 
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Abstract

Dimethylborane was used to hydroborate alkenes regiospecifically. The resultant dimethylalkylboranes react with ammonium hydroxide and sodium hypochlorite to yield isomerically pure alkylamines.

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