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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 21, 1991 - Issue 1
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Original Articles

A New Synthetic Route to Methylenomycin B Via Rhodium(II)-Mediated Decomposition of α,β-Unsaturated α'-Diazoketones

Paolo Ceccherelli Istituto di Chimica Organica, Facolta' di Farmacia Universita' degli Studi, 06100, Perugia, Italy
,
Massimo Curini Istituto di Chimica Organica, Facolta' di Farmacia Universita' degli Studi, 06100, Perugia, Italy
,
Maria Carla Marcotullio Istituto di Chimica Organica, Facolta' di Farmacia Universita' degli Studi, 06100, Perugia, Italy
&
Ornelio Rosati Istituto di Chimica Organica, Facolta' di Farmacia Universita' degli Studi, 06100, Perugia, Italy
Pages 17-23 | Received 25 Oct 1990, Published online: 24 Sep 2006
 
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Abstract

A new synthesis of methylenomycin B, involving Rh(II)-catalyzed, intramolecular carbon-hydrogen insertion of diazoketone 2c, derived from 2,3-dimethyl-2-butenoic acid 2b, is reported.

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