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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 22, 1992 - Issue 17
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Original Articles

Iron-Mediated Synthesis of t-Butyl-N-(Arlyoxy)Carbamates

Michael S. Holden Department of Chemistry, Dickinson College, PO Box 1773, Carlisle, PA, 17013-2896
&
Kristina A. Cole Department of Chemistry, Dickinson College, PO Box 1773, Carlisle, PA, 17013-2896
Pages 2579-2586 | Received 30 Apr 1992, Published online: 23 Sep 2006
 
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Abstract

The anion of t-butyl-N-hydroxycarbamate displaces halogens from (η6-haloarene)(η5-cyclopentadienyliron) salts. The resulting complexes are demetallated by photolysis in sunlight to generate t-butyl-N-(aryloxy)carbamates.

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