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Synthetic Communications
An International Journal for Rapid Communication of Synthetic Organic Chemistry
Volume 25, 1995 - Issue 23
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Original Articles

Reaction of bis-Lactone in Rigid Polycycles with Alkyl Lithiums. Synthesis of Novel Oxa-Cace Compounds

Subrata Sarkar Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, India
&
Subrata Ghosh Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Calcutta, 700 032, India
Pages 3723-3728 | Received 27 Mar 1995, Published online: 23 Sep 2006
 
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Abstract

Reaction of bis-lactone embodied in the rigid tircyclo [5.2.1.02,6] decane 5 with MeLi and t-BuLi produced the novel oxa-cage compounds 9 and 11 instead of the expected ketones 6.

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